Damascene vs Subtractive Etch Interconnects: Key Differences

Subtractive etch interconnects are formed by depositing a metal film over the whole surface, removing the unwanted parts by dry etching through a resist pattern, and filling the gaps between the remaining lines with dielectric; this method was long used for aluminum wiring. The damascene process works in the opposite order: trenches are first etched into the dielectric, metal is filled in, and the excess metal is removed by CMP. Copper hardly forms volatile compounds and is difficult to dry etch, so damascene became the standard for copper wiring. For the finest wires, forming ruthenium or other metals by etching is also being studied.

AspectDamascene processSubtractive etch interconnect
Process orderDeposit dielectric → etch trenches and via holes → barrier metal and seed layer → copper plating → remove excess by CMPDeposit metal film → lithography → dry etch the metal → fill between lines with dielectric and planarize
What is etchedDielectricMetal film
Main metalCopper (Cu)Aluminum (Al-Cu alloy). Ruthenium and others are also being studied for the finest wires
Metal fillTrenches are filled by electroplating. Filling narrow trenches without gaps (voids) is a challengeOnly a flat film made by sputtering or a similar method is needed
Dielectric fillThe dielectric is deposited flat first, so it is rarely a problemNarrow gaps between lines must be filled with dielectric without voids (HDP-CVD and similar methods have been used)
CMPEssential. Removes the copper and barrier metal outside the trenches, separating each lineNot used to pattern the metal. Used to planarize the dielectric
Barrier layerTrench bottoms and sidewalls are lined with TaN/Ta or similar to prevent copper diffusion. In narrow lines it takes up a larger share of the cross sectionDiffusion is less of a problem with aluminum; Ti/TiN or similar films are stacked above and below
How vias are madeIn dual damascene, line trenches and vias are filled at the same time and finished with a single CMPVias are opened in a separate step, filled with tungsten or similar and planarized by CMP before the next wiring layer is made
Challenges for fine wiresAs lines narrow, copper resistivity rises (size effect) and the barrier layer takes a larger sharePrecision in etching thin metal lines, and filling between lines with dielectric, are challenges

Figures are typical orders of magnitude and vary by process generation and product.

When to use which

Damascene process
When making copper interconnects. Multilevel interconnects in advanced LSIs that need low-resistance wiring with high resistance to electromigration.
Subtractive etch interconnect
When making aluminum interconnects. Products with few wiring layers, or relatively wide wires. It is also being studied as a method for the finest wires using ruthenium or other metals.
Trend
Today's advanced LSIs make most of their wiring with copper dual damascene. For the finest layers, forming metals whose resistance rises less and that allow thinner barrier layers by etching is being reconsidered.

FAQ

Why is copper difficult to dry etch?

Because the copper compounds formed by reaction with chlorine and other etch gases are hard to volatilize and remain on the surface near room temperature. They can be volatilized at high temperatures, but the resist and other materials cannot withstand that, making practical patterning difficult. That is why copper is shaped by filling trenches and using CMP.

What is dual damascene?

A method in which both the line trenches and the via holes connecting to the layer below are formed in the dielectric, filled at the same time in a single copper plating step, and finished with a single CMP. It requires fewer steps than single damascene, which makes trenches and vias separately.

Where does the name damascene come from?

It comes from damascening, a decorative inlay technique in which grooves are carved into a metal surface and filled with another metal. The name was chosen because the process of filling trenches in the dielectric with metal resembles this technique.

Will interconnects return to subtractive etching?

Not entirely. Layers with wide wires will continue to be made with copper damascene. For layers with very small line widths, rising copper resistivity and barrier layer thickness become problems, so methods that pattern ruthenium or other metals by etching are being studied.

Check your understanding

Which correctly describes the damascene process commonly used to form copper wiring?

  1. ACopper film is patterned directly by dry etching
  2. BTrenches are formed in the insulator, filled with copper, and the excess copper is removed by CMP
  3. CCopper is thermally oxidized to form the wiring shape
Show answer and explanation

Answer: B. Trenches are formed in the insulator, filled with copper, and the excess copper is removed by CMP

In damascene processing, trenches shaped like the wiring are etched into the dielectric, barrier and copper seed layers are sputtered, and copper is electroplated to fill them. CMP then removes excess copper and barrier from the surface, leaving metal only in the trenches. The name comes from the ancient inlay craft of Damascus, in which gold or silver was set into grooves cut in metal. Filling trenches and vias together is called dual damascene.

What is the method called that fills wiring trenches and vias with copper at the same time and finishes them with a single CMP step?

  1. ASingle damascene process
  2. BEtch-back process
  3. CDual damascene process
Show answer and explanation

Answer: C. Dual damascene process

Dual damascene patterns both via holes and wiring trenches into the dielectric, then fills them together with barrier, seed and electroplated copper and finishes with a single CMP. Compared with single damascene, which builds vias and lines separately, it saves one round each of deposition, plating and CMP, and avoids a barrier interface between via and line, benefiting resistance and reliability. Variants differ in whether vias or trenches are opened first.

What is the main reason the wiring material of advanced ICs was changed from aluminum (Al) to copper (Cu)?

  1. ALower resistivity and higher electromigration resistance
  2. BIt is easier to process by dry etching
  3. CIts adhesion to oxide is so high that no barrier layer is needed
Show answer and explanation

Answer: A. Lower resistivity and higher electromigration resistance

Copper's resistivity (about 1.7 µΩ·cm) is roughly 60% of aluminum's (about 2.7 µΩ·cm), cutting wiring delay and power, and its higher melting point makes atoms less mobile, improving electromigration resistance by an order of magnitude or more. IBM announced production in 1997, and copper became mainstream around the 0.13 µm generation. Because copper forms no volatile compounds for dry etching and diffuses readily into dielectrics, it is formed by damascene and encased in Ta/TaN barriers.

  1. What is the main purpose of barrier metals such as Ta and TaN in copper wiring?
  2. What is an advantage of metals such as ruthenium (Ru), being considered as alternatives to copper for fine wiring?
  3. In Cu interconnect CMP, why is polishing generally divided into stages?

Practice Interconnect processes questions

Key terms explained

Damascene process
A method of forming interconnects by etching trenches in an insulating film, filling them with metal, and removing the excess metal by CMP. Used for copper wiring.
Dual damascene
Forming both the trench for a wire and the hole for a via in the insulator, filling them with copper together and finishing with a single CMP step. It reduces process steps.
CMP
Chemical mechanical polishing. Planarizes the wafer surface by combining the chemical action of a slurry with mechanical polishing by a pad.
Barrier metal
A thin metal film around copper wiring that prevents copper from diffusing into insulating films or silicon, such as Ta or TaN.
Electromigration
The movement of metal atoms in interconnects caused by electric current. It creates voids and hillocks that lead to open or short circuits.

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