Furnace Anneal vs RTA vs Laser Anneal: Time Scale, Diffusion, Activation and Uses

After ion implantation, wafers are annealed to repair crystal damage and to place dopants on lattice sites so that they become electrically active (activation). The longer the wafer stays hot, however, the more the dopants diffuse and the deeper the junctions become. A furnace anneal heats many wafers together in a furnace for tens of minutes to hours. RTA (rapid thermal annealing) heats one wafer at a time with lamps for only a few seconds, and spike annealing, which barely holds at the peak temperature, belongs to the same family. Laser and flash lamp annealing heat only a thin layer near the wafer surface for a millisecond or less. Shorter heating means less diffusion, so as transistors have shrunk, processes have moved toward shorter anneals.

AspectFurnace annealRTA / spike annealLaser / flash lamp anneal
Heating timeTens of minutes to hoursSeconds to tens of seconds; in a spike anneal, the time near the peak temperature is roughly 1 to 2 secondsA millisecond or less: typically around a millisecond for flash lamps, and milliseconds down to nanoseconds for lasers, depending on the method
Ramp rateSlow, typically a few to around ten-odd °C per minuteFast, typically tens to hundreds of °C per secondOnly the surface heats extremely fast, then cools quickly as heat flows into the wafer
Processing unitMany wafers at once (batch)One wafer at a time (single wafer)One wafer at a time; flash lamps heat the whole surface at once, lasers scan a beam across it
Heated regionAll wafers in the furnace reach a nearly uniform temperatureThe whole wafer thickness reaches nearly the same temperatureOnly a thin layer near the surface reaches the peak temperature; the bulk stays cooler (at the preheat temperature for flash lamps) and acts as a heat sink
Thermal budgetLargeModerate, far smaller than a furnace annealVery small
Dopant diffusionLarge; junctions get deeper and transient enhanced diffusion (TED) has a strong effectSuppressed; shallow junctions are possible, though some diffusion remainsAlmost none; the as-implanted profile is largely preserved
ActivationRoughly capped by solid solubility at that temperature; raising the temperature also increases diffusionHigh activation, since high temperatures can be usedHigh activation from very high temperature for a very short time; metastable activation above equilibrium solid solubility is possible, but part of it tends to deactivate in later thermal steps
Repair of crystal defectsEasy to repair with the long time availableRepairs most defectsDefects may remain because the time is so short; often combined with a spike anneal
Typical usesWell drive-in, film densification, relatively low-temperature forming gas anneals and similar; furnaces of the same type are also used for thermal oxidation and LPCVDSource/drain activation, silicide formation, thin oxide growth and nitridationActivation of shallow source/drain and extension regions in advanced logic (combined with spike anneals), and steps where lower layers must not be heated (such as the backside of IGBTs)

Figures are typical orders of magnitude and vary by process generation and product.

When to use which

Furnace anneal
Suits cases where dopants should diffuse well, such as forming deep wells, and where many wafers need slow, uniform processing. It is no longer used to activate shallow junctions because it causes too much diffusion.
RTA / spike anneal
The standard method for source/drain activation. It activates dopants at high temperature while keeping the heating time on the order of seconds to limit diffusion. It is also used for silicide formation.
Laser / flash lamp anneal
Used in advanced transistors that must keep junctions very shallow, to activate dopants with almost no diffusion. Because it heats only the surface, it also suits steps where lower layers or backside structures must not be damaged.

FAQ

What is a thermal budget?

A way of expressing how much heat a wafer receives as a combination of temperature and time. The diffusion distance of a dopant is roughly the square root of the diffusion coefficient times time (√(Dt)), and the diffusion coefficient grows exponentially with temperature. So diffusion is smaller for shorter time at the same temperature, or lower temperature for the same time.

Are RTA and RTP the same?

RTP (rapid thermal processing) is the general term for heating one wafer at a time for a short period with lamps or similar sources. When the purpose is annealing, such as activation after ion implantation, it is called RTA (rapid thermal annealing). Growing a thin oxide in the same kind of tool is called RTO.

How is a spike anneal different from a regular RTA?

A regular RTA holds the peak temperature for seconds to tens of seconds, while a spike anneal starts cooling as soon as the peak is reached, with almost no hold. It activates dopants at high temperature while shortening the time spent hot, to limit diffusion.

Why not use laser annealing alone?

Because the heating time is so short, implant damage may not be fully repaired, and dopants activated above equilibrium solid solubility tend to partly deactivate in later thermal steps. Light absorption also varies with the pattern, so the temperature can vary from place to place. For these reasons, it is combined with spike anneals and used with limits on the temperature of later steps.

Check your understanding

What is the main purpose of annealing (heat treatment) after ion implantation?

  1. ATo evaporate and remove the implanted dopants
  2. BTo repair crystal damage and place dopants on lattice sites to activate them electrically
  3. CTo grow a thick oxide on the wafer surface
Show answer and explanation

Answer: B. To repair crystal damage and place dopants on lattice sites to activate them electrically

Implanted ions disrupt the silicon lattice and mostly sit at interstitial sites where they do not act as donors or acceptors, so they are largely electrically inactive right after implantation. Annealing repairs the damage and moves dopants onto lattice sites, activating them. To avoid excessive diffusion, lamp-based RTA lasting seconds or flash-lamp and laser anneals lasting milliseconds or less are used.

Which is a characteristic of laser annealing?

  1. AIt heats the whole wafer uniformly for a long time
  2. BIt heats slowly at low temperature
  3. CIt heats only near the wafer surface for an extremely short time, achieving high activation while limiting diffusion
Show answer and explanation

Answer: C. It heats only near the wafer surface for an extremely short time, achieving high activation while limiting diffusion

Laser annealing heats only the near-surface region with laser light for microseconds to nanoseconds, reaching above 1000 °C (approaching melting in some cases). High activation is achieved before dopants can diffuse appreciably, yielding shallow, low-resistance junctions. Because heat does not penetrate deeply, it is also used where underlying layers must be protected, such as forming IGBT backside layers or upper-tier transistors in stacked structures.

What is the heat treatment called that heats wafers one at a time to high temperature for a few seconds using lamps or similar sources?

  1. ABatch furnace annealing
  2. BRTP (rapid thermal processing)
  3. CCMP
Show answer and explanation

Answer: B. RTP (rapid thermal processing)

RTP heats and cools wafers with halogen lamps at tens to hundreds of degrees per second, holding temperatures above 1000 °C for only seconds. The short time at temperature allows dopant activation after implantation and thin oxide growth while limiting diffusion. Flash-lamp and laser anneals, which shrink heating to milliseconds or less, are used to form ultra-shallow junctions at advanced nodes.

  1. What is the phenomenon called in which diffusion of boron and other dopants is temporarily accelerated early in annealing because of interstitial silicon created by implantation?
  2. When dopants are activated by annealing, which property sets the upper limit of the concentration that can be electrically activated?
  3. How does the diffusion coefficient of dopants in silicon depend on temperature?

Practice Ion implantation questions

Key terms explained

Annealing
Heat treatment. Used to repair crystal damage after ion implantation and to activate dopants, among other purposes.
RTP (rapid thermal processing)
Heating single wafers to high temperature for a few seconds, typically with lamps. It allows annealing and thin oxide growth while limiting unwanted dopant diffusion.
Spike anneal
An anneal that ramps the wafer quickly to a high temperature and cools it again with almost no hold time. It activates dopants while limiting diffusion, for shallow junctions.
Laser anneal
Heating only the near-surface region of a wafer for an extremely short time with laser light. It achieves high activation with almost no diffusion.
Transient enhanced diffusion (TED)
A temporary speed-up of boron and other dopant diffusion early in post-implant annealing, caused by excess silicon interstitials from the implant. It hinders the formation of shallow junctions.
Solid solubility
The maximum concentration of an impurity that can dissolve in a crystal at a given temperature. It sets the upper limit of electrically active dopant concentration.
Ion implantation
A technique that ionizes impurities, accelerates them and implants them into the wafer. The dose and depth can be controlled precisely.

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