Silicon wafers
Which is a known effect of adding a trace of nitrogen during CZ crystal growth (nitrogen doping)?
- AIt promotes oxygen precipitation and shrinks the voids formed by clustered vacancies in the crystal
- BThe crystal diameter automatically increases
- CThe crystal becomes heavily n-type
Show answer and explanation
Answer: A. It promotes oxygen precipitation and shrinks the voids formed by clustered vacancies in the crystal
Adding a trace of nitrogen makes nuclei for oxygen precipitation form more easily, improving gettering capability, and it shrinks void defects formed by clustering vacancies so they are easier to eliminate in later heat treatment. The amount added is very small, and its effect as a donor is hardly a concern.
- A. Correct. It promotes oxygen precipitation and shrinks voids.
- B. The diameter is set by the pulling conditions.
- C. The amount is tiny, so conductivity type and resistivity are hardly affected.