Oxidation and diffusion
When boron-doped silicon is thermally oxidized, how does the boron concentration on the silicon side near the interface tend to change?
- AIt decreases, because boron is readily taken into the oxide
- BIt increases, because boron is pushed out to the interface
- CIt does not change
Show answer and explanation
Answer: A. It decreases, because boron is readily taken into the oxide
At the Si/SiO2 boundary, each dopant has a characteristic ratio in which it divides between the two sides (segregation). Boron is readily taken into the oxide, so its concentration near the silicon surface decreases. Phosphorus and arsenic, in contrast, are pushed into the silicon and tend to pile up near the interface.