Silicon wafers
When a doped crystal is pulled by the CZ method, the dopant concentration tends to be higher toward the bottom of the crystal (later in the pull). Why?
- ABecause gravity makes the impurities sink
- BBecause many dopants have segregation coefficients below 1, so dopants that are not readily incorporated become concentrated in the melt
- CBecause the temperature is lower later in the pull
Show answer and explanation
Answer: B. Because many dopants have segregation coefficients below 1, so dopants that are not readily incorporated become concentrated in the melt
As the crystal solidifies, many dopants are not readily incorporated (segregation coefficient below 1) and remain in the melt. As pulling proceeds, the dopant concentration in the melt rises, so later parts of the crystal have higher dopant concentrations and lower resistivity. Resistivity therefore varies with position along the ingot.