Etching
Why is it difficult to pattern copper wiring directly by dry etching?
- ABecause copper does not conduct electricity
- BBecause copper is too soft
- CBecause copper halides are not volatile, so the reaction products cannot be removed
Show answer and explanation
Answer: C. Because copper halides are not volatile, so the reaction products cannot be removed
Aluminum reacts with chlorine to form volatile aluminum chloride and can be dry-etched, but copper chlorides and similar compounds are not volatile and remain on the surface. Copper wiring is therefore made without etching by the damascene process, filling trenches and polishing by CMP.