Etching
Exposing silicon to XeF2 gas and an argon ion beam simultaneously etches it far faster than the sum of either alone. What property of dry etching does this show?
- AEtching depends only on temperature
- BIons play no role in etching
- CThe synergy between ions and radicals (ion assistance)
Show answer and explanation
Answer: C. The synergy between ions and radicals (ion assistance)
Coburn and Winters showed that etch rates are small with XeF2 alone or argon ions alone, but increase greatly when both are applied together. This synergy, in which ion bombardment assists surface reactions and product desorption, is why reactive ion etching can be both fast and anisotropic.
- A. It cannot be explained by temperature alone.
- B. It shows that ions greatly accelerate the reaction.
- C. Correct. It shows the synergy between ions and radicals.