CMP and cleaning
What is the state of a silicon surface whose last cleaning step was dilute hydrofluoric acid?
- AThe surface is hydrogen-terminated and becomes hydrophobic
- BThe surface is covered with metal
- CIt is covered with a thick oxide and becomes hydrophilic
Show answer and explanation
Answer: A. The surface is hydrogen-terminated and becomes hydrophobic
A silicon surface from which oxide has been removed with dilute HF is terminated with hydrogen atoms and becomes hydrophobic, repelling water. Such a surface temporarily resists oxidation, but particles adhere to it easily, so the time until the next step is controlled.
- A. Correct. It becomes hydrogen-terminated and hydrophobic.
- B. HF cleaning does not coat the surface with metal.
- C. HF removes oxide, so it does not leave an oxide coating.