Semiconductor physics
Why is the intrinsic Fermi level of silicon slightly offset from the exact center of the band gap?
- ABecause the band gap disappears as the temperature rises
- BBecause the effective densities of states (effective masses) of the conduction and valence bands differ
- CBecause silicon crystals always contain impurities
Show answer and explanation
Answer: B. Because the effective densities of states (effective masses) of the conduction and valence bands differ
In an intrinsic semiconductor, the Fermi level sits where the electron and hole densities are equal. Because the effective densities of states of the conduction and valence bands differ due to different effective masses, the intrinsic Fermi level shifts slightly from the center. In silicon the shift is only about 0.01 eV at room temperature, so it can be treated as nearly mid-gap.
- A. The band gap does not disappear when temperature rises.
- B. Correct. The difference in effective densities of states causes a small shift.
- C. The intrinsic Fermi level is defined for the ideal case without impurities.